Bis(4-benzoyl-3-methyl-1-phenyl-4,5-dihydro-1H-pyrazol-5-olato-κ2 O,O′)(methanol-κO)dioxidouranium(VI) methanol monosolvate
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چکیده
In the title compound, [U(C(17)H(13)N(2)O(2))(2)O(2)(CH(3)OH)]·CH(3)OH, the U(VI) ion is coordinated by seven O atoms in a distorted pentagonal-bipyramidal geometry with two 3-methyl-1-phenyl-4-benzoyl-4,5-dihydro-1H-pyrazol-5-olate groups with two O atoms in a bidentate chelating coordination mode and by three O atoms, one of which is from a methanol ligand. The crystal packing can be described by alternating layers of complex mol-ecules along the a axis. The structure is stabilized by O-H⋯N and O-H⋯O hydrogen bonding and van der Waals inter-actions.
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Bis[4-(4-chlorobenzoyl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2 O,O′]bis(methanol-κO)nickel(II)
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